WebDec 1, 2024 · When plant intact tissue is damaged, glucosinolates and myrosinase are brought together to generate glucose and an unstable aglycone intermediate, … WebThe thiohydroxamate-O-sulfonate can undergo spontaneous rearrangement into different possible products: isothiocyanates, nitriles and elemental sulfur, thiocyanates, epithionitriles, oxazolidine-2-thiones or indolyl compounds depending upon the structure of the side chain and the pH environment (Holst and Williamson
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WebApr 12, 2024 · Abstract The radical copolymerization of sodium styrene sulfonate with vinyl saccharide 2-deoxy-2-methacrylamido-D-glucose in water is studied. For sodium styrene sulfonate and 2-deoxy-2-methacrylamido-D-glucose the reactivity ratios are found to be r1 = 1.58 ± 0.05 and r2 = 0.18 ± 0.01, respectively. Water-soluble copolymers of varying … WebThe unstable aglycone intermediate (the thiohydroxamate-O-sulfonate) undergoes spontaneous rearrangement into different possible products: isothiocyanates (ITCs), … contact shbp
Glucosinolate hydrolysis and the formation of GLS-HPs.
Web(thiohydroxamate –O-sulfonate) that can rearrange spontaneously to form different possible products. Therefore, in addition to isothiocyanates, nitriles are also formed, as well as thiocyanates and epithionitriles to a smaller degree 4]. [The type and ratio of the Web73 moiety of a glucosinolate. This leaves the unstable aglycone, thiohydroxamate-O-sulfonate, 74 which rearranges to form an isothiocyanate or other breakdown products [12, 13]. Other 75 isothiocyanates such as 4-methoxyphenyl isothiocyanate and methyl isothiocyanate are 76 synthetically produced and not naturally occurring. 77 http://www.plantarchives.org/SPL%20ISSUE%2024-2/458__2758-2763_.pdf contact sharri markson